What I do, is rip it down the middle first leaving 2 equal halves. But then rather than using the chainsaw to saw down the middle of those halves, rendering quarters, which messes up the best two boards in each half. I usually move off center about 6" - 10" for my next chainsaw cuts. This will be the side down on the band mill. Then the first cut on the mill will be about the same distance above the pith, then I set that cant aside. Then I cut that main cant as it sits on the mill. This will start and end up with some nice rift lumber toward the top and bottom, and the best QS in the middle. But you could move right to cutting near the pith getting the best QS in the middle, then tipping up the edge of those cants with wedges for more QS.
The cuts on the other cants will be obvious.
Oh, one last thought. Usually a log of that size will have root buttresses which may make it somewhat square on up the first log. the definition for Medullary rays says they radiate out from the pith. However on a larger out of round log, it might be better describes as perpendicular to the cambium. So they can bend outward toward the surface in a buttress. This can end up rendering some partial QS as your finishing up the two cants from the sides of the two halves. Making your first halving cut with the chainsaw through the thinnest part of the log usually takes advantage of what I'm trying to share, so don't try to overthink it if you don't understand that.